The reaction of tris(trimethylsilyl)sila
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M. Ballestri; C. Chatgilialoglu; N. Cardi; A. Sommazzi
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Article
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1992
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Elsevier Science
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French
⚖ 268 KB
Tris(trimethylsilyl)silane, in contrast with tributyltin hydride, reduces acid chlorides to the corresponding decarboxylated hydrocarbons via a free radical mechanism. This methodology could be a viable alternative to Barton's decarboxylation reaction. Tributyltin hydride reacts spontaneously at amb