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Reaction of achiral titanium Z-enolates with chiral α-silyloxy aldehydes

✍ Scribed by Cristina Esteve; Mònica Ferreró; Pedro Romea; Fèlix Urpí; Jaume Vilarrasa

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
184 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

Aldol reactions between the putative Z-enolate derived from 2-methyl-3-pentanone and several chiral ot-tert-butyldiphcnylsilyioxy aldehydes have been studied. The stereoehemical outcome suggests that stereoelectronic effects play a dominant role in these reactions and the results can be accommodated by the Felkin model, with gauche pentane interactions being less important.

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