Reaction of acetals and trialkylsilanes catalyzed by trimethylsilyl trifluoromethanesulfonate. A simple method for conversion of acetals to ethers
β Scribed by T. Tsunoda; M. Suzuki; R. Noyoro
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 352 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The allylation of acetals using allyltrimethylsilane is efficiently catalyzed by bismuth triflate (1.0 mol%). The reaction proceeds smoothly at room temperature to afford the corresponding homoallyl ether in good yield. The mild reaction conditions, the low toxicity of bismuth salts, and the high ca
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