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Reaction of a silyl?copper reagent with acetylenes: a new synthesis of vinylsilanes

✍ Scribed by Fleming, Ian; Roessler, Felix


Book ID
118004371
Publisher
The Royal Society of Chemistry
Year
1980
Tongue
English
Weight
236 KB
Volume
6
Category
Article
ISSN
0022-4936

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Reaction of (trimethylstannyl) copper re
✍ Edward Piers; J.Michael Chong; Howard E. Morton πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 303 KB

The stereochemical course of the conjugate addition of various (trimethylstannyl)cuprate (or copper) reagents to cr,B-acetylenic esters is dependent on the constitution of the reagent and on the structure of the substrate. Recently, it was reported 1 that the conjugate addition of lithium (phenylth