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Reaction of a cyclic hydroxamic acid from gramineae with thiols

✍ Scribed by Hermann M. Niemeyer; Luis J. Corcuera; Francisco J. Pérez


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
233 KB
Volume
21
Category
Article
ISSN
0031-9422

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Reaction of cyanide with hydroxamic acid
✍ Thomas Emery 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 364 KB

At high pH primary hydroxamic acid-iron complexes react rapidly with potassium cyanide to yield a deep blue iron complex. Secondary, or N-substituted, monohydroxamic acid-iron complexes also react with loss of the red color typical of these complexes but with no formation of the blue product. Under