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Reaction of 6-aryl-2,2-dimethyl-1,3-dioxin-4-ones with cyanoamino compounds

✍ Scribed by Yu. S. Andreichikov; D. D. Nekrasov; M. A. Rudenko; O. V. Vinokurova

Publisher: Springer US
Year: 1989
Tongue: English
Weight: 246 KB
Volume: 25
Category: Article
ISSN: 0009-3122
DOI: 10.1007/bf00487311

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2-Alkylidene-benzo[1,3]dioxin-4-ones: a

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A new class of compounds, 2-alkylidene-benzo[1,3]dioxin-4-ones, have been synthesised by cyclisation of the corresponding o-acyloxy benzoyl chlorides with triethylamine. The 2-methylene-benzo[1,3]dioxin-4-one acts as a prodrug for aspirin and is a useful intermediate in the synthesis of new aspirin