Reaction of 5-Amino-2,3-dicyano-1,4-naphthoquinone with Arylamines
✍ Scribed by Koichi Takagi; Masaru Matsuoka; Yuji Kubo; Teijiro Kitao
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 394 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0143-7208
No coin nor oath required. For personal study only.
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## Abstract magnified image The usefulness of 3‐iodoindole available for introduction of an indole unit is presented. The reaction of 3‐iodoindole with 2‐bromo(or methyl)‐1,4‐naphthoquinone in acetic acid gave 2‐bromo(or methyl)‐3‐(3‐indolyl)‐1,4‐naphthoquinone. On the other hand, the reaction of 3
## Abstract Treatment of 4‐chloro‐5__H__‐1,2,3‐dithiazole‐5‐thione with alkyl 3‐alkyl (or aryl)‐3‐amino‐2‐propenoates in the presence of pyridine (2 equivalents) in dichloromethane at reflux gave 2‐[2‐(1‐alkenylsulfanyl‐1‐alkoxy‐carbonyl‐2‐amino)‐1,2‐dicyanovinylsulfanyl]‐**4** and‐1,2‐dicyanovinyl