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Reaction of 3-nitro-4,5-dihydro-6H-1,2-oxazine N-oxide with acetylenes

✍ Scribed by I. E. Chlenov; I. L. Sokolova; B. N. Khasapov; V. M. Novikov; N. F. Karpenko; A. U. Stepanyants; V. A. Tartakovskii


Book ID
112438906
Publisher
Springer
Year
1974
Tongue
English
Weight
326 KB
Volume
23
Category
Article
ISSN
1573-9171

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1 ,ZOxazines, bis(trimethylsily1)amino-substituted / Hydrogenolysis / Deprotonation / Alkylation / Deuteration 1,2-Oxazine 1 was converted into an unusual condensation product 5 by treatment with tetra-n-butylammonium fluoride. The hydrogenolysis of 1 with Pd/C as catalyst provided the expected prim