Reaction of 3-chloro-3-methyldiazirines with hydrogen atoms
β Scribed by Burkholder, C. D.; Jones, W. E.; Wasson, J. S.; Liu, M. T. H.
- Book ID
- 127375373
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 255 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
3-Bromo-3-methyldiazirine readily undergoes exchange reactions with F-, MeO-, CN-, or Ng-. New carbene precursors can thus be prepared. 3-Halo-3-aryldiazirines undergo synthetically useful exchange reactions with strong nucleophiles that proceed via tight diazlrinium halide ion pairs and provide co
The mechamsm of rexnon of atomic hydrogen wth CH,Br has been exammed by product analysis m a static system In a vessel coaled wrh NaOH to remove HBr. quantum ytelds close IO u-my are found for C,H, formatIon\_ H+CH,Br + CH, + HBr XH, -c C2 H, The reaction scheme 1s modelled by assuming that surLxe l