Reaction of 3-Aryl-2-cyanothioacrylamides with Dimethyl Acetylenecarboxylate, Methyl Propiolate, and N-Phenylmaleimide.
โ Scribed by T. G. Deryabina; M. A. Demina; N. P. Belskaya; V. A. Bakulev
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 23 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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## Abstract A new PPh~3~โcatalyzed synthesis of alkyl 2โ[aryl(tosylimino)methyl]acrylates from propiolate and __N__โtosylimine has been developed. Deuteriumโlabelling experiments show that the reaction mechanism involves several hydrogenโtransfer processes, which are not the turnoverโlimiting step
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