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Reaction of 2,4-disubstituted 1,3-dioxolanes with dihalocarbenes

โœ Scribed by M. S. Klyavlin; T. K. Tkachenko; L. P. Salagaeva; S. S. Zlotskii; D. L. Rakhmankulov


Publisher
Springer US
Year
1991
Tongue
English
Weight
180 KB
Volume
27
Category
Article
ISSN
0009-3122

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SnCl4-mediated reaction of ozonides with
โœ Patrick H. Dussault; Xuejun Liu ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 196 KB

SnC14-mediated reaction of ozonides (1,2,4-trioxolanes) with aUyltrimethylsilane furnishes trimethylsilylmethyl-l,2-dioxolanes via metalated carbonyl oxides. The carbonyl oxides can arise through initial ionization of either the ether or peroxide oxygens.