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Reaction of 2-thienyl copper with iodobenzene

โœ Scribed by Martin Nilsson

Book ID
104223384
Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
172 KB
Volume
7
Category
Article
ISSN
0040-4039

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Attempts to homocouple 1,3-bis(2-hydroxyhexafluoro-2-propyl)-5iodobenzene (diol iodide) with copper fail to give the desired biphenyl tetrol. However, the dimethyl ether derivative of the diol iodide reacts smoothly with copper to give the biphenyl tetramethyl ether in good yields. The diacetate der