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Reaction of 2-halo-5-nitropyridines with hydroxide ion in dimethyl sulfoxide

✍ Scribed by Reinheimer, J. D.; Mayle, L. L.; Dolnikowski, G. G.; Gerig, J. T.


Book ID
120080813
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
471 KB
Volume
45
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


Kinetics and reactivity of substituted a
✍ Ali A. El-Bardan; Gehan M. El-Subruiti; Fatma El-Zahraa M. El-Hegazy; Ezzat A. H πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 87 KB

## Abstract The kinetics of the reaction of substituted anilines with 2‐chloro‐5‐nitropyridine were studied in dimethyl sulfonide (DMSO) and dimethyl formamide (DMF) at different amine concentrations and temperatures in the range 45–60Β°C. In both solvents the reaction was not a base‐catalyzed one.

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Substitution reactions of some parasubstituted anilines with 2-chloro-5nitropyridine and 2-bromo-5-nitropyridine were carried out conductometrically in dimethylsulfoxide/acetonitrile mixtures. The correlation of second order rate constants with Hammett's substituent constants yields a fairly linear