Reaction of 2-acyl-6-methylbenzo[b]furan-3-acetic acids derivatives with hydrazine
✍ Scribed by Valery S. Tolkunov; Igor F. Perepichka; Vladimir I. Dulenko
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2005
- Tongue
- English
- Weight
- 157 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0022-152X
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✦ Synopsis
Abstract
Reaction of 2‐acyl‐6‐methylbenzo[b]furan‐3‐acetic acids and their derivatives such as amides and esters with hydrazine does not give expected 1‐alkyl‐5__H__‐benzofuro[2,3‐e]diazepin‐4‐ones ones but results in 2‐amino‐7‐methyl‐2__H__‐benzo[4,5]furo[2,3‐c]pyridin‐3‐ones or (3‐R‐6‐methylbenzo[b]furan‐2‐yl)alkyl ketone azines.
📜 SIMILAR VOLUMES
-ones (3) were obtained from some 2,3-dihydro-furan-2,3-diones with a few Wittig reagents ( 2). The compounds of 3 with glycin and hydrazines (4a,b) produced 2,3-dihydro- . All the reaction mechanisms were discussed by utilizing the similar reaction pathways. Structures of these compounds were deter