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Reaction of 1,2-dehydro-o-carborane with acetylenes. Ene reactions and cycloaddition to give an analog of benzocyclobutadiene

✍ Scribed by Cunningham, Rebecca J.; Bian, Nanying; Jones, Maitland Jr.


Book ID
126463333
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
167 KB
Volume
33
Category
Article
ISSN
0020-1669

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Diastereoselective Reaction of a 1-Phosp
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solution and a mixture of 5 or 6 and protonated pyridine precipitated. The latter was removed by fractional recrystallization from CH,CI,!Et,O. Synthesis of 5 and 6 from 2: A solution of 2.5 mmol of 2 in 20 mL of CH,CI, was treated with 2 5 inmol of Me,SiOTf. Then 6 mmol of diazo ester 3 or 4 was a