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Reaction of 1,1-dimethylallene with NiMo(CO)4(.eta.-C5H5)(.eta.-C5H4Me). Isomerization of the product to NiMo(.mu.-CO)(CO){.mu.-.eta.1,.eta.3-C(Me)C(Me)CH2}(.eta.-C5H5)(.eta.-C5H4Me): a 1,2-methyl migration or a 1,4-proton shift?

โœ Scribed by Chetcuti, Michael J.; McDonald, Steven R.; Rath, Nigam P.

Book ID
126770567
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
432 KB
Volume
8
Category
Article
ISSN
0276-7333

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๐Ÿ“œ SIMILAR VOLUMES

Reactions of compounds containing nickel
Reactions of compounds containing nickel-nickel, nickel-molybdenum, and nickel-tungsten bonds with allene and 1,1-dimethylallene. X-ray diffraction studies of the .pi.-allylic complexes NiMo(CO)2 {.mu.-.eta.3,.eta.3-C9H12} (.eta.5-C5H5) (.eta.5-C5H4Me) and NiMo(.mu.-CO)(CO) {.mu.-.eta.1,.eta.3-C(Me)-C(Me)-CH2} (.eta.5-C5H5) (.eta.5-C5H4Me)(Ni-Mo) [Erratum to document cited in CA115(1):9028r]
โœ Chetcuti, Michael J.; Fanwick, Phillip E.; Mcdonald, Steven R.; Rath, Nigam N. ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 92 KB