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Reaction of 1-Trimethylsilyl-3-chloro-1-propyne with α-Nitroacetophenone.

✍ Scribed by O. I. Yurchenko; T. N. Dybova; N. V. Gritsai; V. D. Buikliskii; E. D. Mel'nikova

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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## Abstract Thermolysis of the “all‐__cis__” compound 1α‐chloro‐2α,3α‐dimethylcyclopropane (A) at 550–607 K and 6–115 torr is a first‐order homogeneous non‐radical‐chain process giving penta‐1,3‐diene (PD) and HCl as products. The Arrhenius parameters are log~10~__A__(sec^−1^) = 13.92 ± 0.08 and __

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## Abstract Poly(1‐trimethylsilyl‐1‐propyne) (PTMSP) membranes have been used to separate ethanol–water mixtures by pervaporation. This polyacetylene is known to present high affinity toward ethanol, showing high selectivity and ethanol permeation flux. The performance of this polymer in the separa