Reactions of Ph(ClCH2)SiH2 with fluoride
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Jean L. Huhmann; Joyce Y. Corey
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Article
📅
1993
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John Wiley and Sons
🌐
English
⚖ 954 KB
The fluoride ion-induced rearrangement of Ph (ClCH,)SiH, was expected to provide either Ph-MeSiHF (migration of hydride) or (PhCH2)SiH2F (migration of phenyl). However, when B u $ I f F -(commercial TBAF) is added to Ph(ClCH2)SiH2, a mixture of fluorine-terminated siloxanes, FPh-MeSiO(PhMeSiO)&MePhF