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Reaction of 1-hydrohexafluoroisobutenyloxytrimethylsilane with fluoride ion sources. 2,2,2’,2’-Tetrakis(trifluoromethyl)divinyl ether

✍ Scribed by A. Yu. Volkonskii; E. M. Kagramanova; E. I. Mysov; N. E. Mysova


Book ID
106519543
Publisher
Springer
Year
2004
Tongue
English
Weight
535 KB
Volume
53
Category
Article
ISSN
1573-9171

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Reactions of Ph(ClCH2)SiH2 with fluoride
✍ Jean L. Huhmann; Joyce Y. Corey 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 954 KB

The fluoride ion-induced rearrangement of Ph (ClCH,)SiH, was expected to provide either Ph-MeSiHF (migration of hydride) or (PhCH2)SiH2F (migration of phenyl). However, when B u $ I f F -(commercial TBAF) is added to Ph(ClCH2)SiH2, a mixture of fluorine-terminated siloxanes, FPh-MeSiO(PhMeSiO)&MePhF