๐”– Bobbio Scriptorium
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Reaction mechanisms in reductions by metal-ammonia solutions

โœ Scribed by A.J. Birch; D. Nasipuri


Publisher
Elsevier Science
Year
1959
Tongue
French
Weight
64 KB
Volume
1
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Ah&net-The mechanism is discussed of the reduction of monobenxenoid comnounds bv means of metals and acohols in liquid ammonia. Contrary to claims in benxothiophene are both readily reducible by this method.


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โœ Valentin Rautenstrauch ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 397 KB

The hypothesis of Pradhan that alkali metal/NH3 reductions of saturated ketones lead to ketone &anions which then deprotonate unreacted ketone can be excluded because the dianions would have been protonated in experiments in which 50-110 equiv of tert.-Bush, Et&L, and H20 were present in the reactio