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Reaction mechanism of poly(vinyl chloride) degradation. Molecular orbital calculations

✍ Scribed by Bacaloglu, Radu; Fisch, Michael H.

Book ID
127370406
Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
769 KB
Volume
1
Category
Article
ISSN
1083-5601

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A~traet--The mechanism of the light-induced degradation of solid poly(vinyl chloride) (PVC) has been investigated, and an overall reaction scheme has been developed, based on values of the quantum yields for the primary photoproducts. Only a very small fraction (0.2%) of the excited polyenes induces