Reaction Mechanism of Apocarotenoid Oxygenase (ACO): A DFT Study
✍ Scribed by Tomasz Borowski; Margareta R. A. Blomberg; Per E. M. Siegbahn
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 866 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The kinetics and mechanisms of the gas‐phase elimination reactions of neopentyl chloride and neopentyl bromide have been studied by means of electronic structure calculations using density functional methods: B3LYP/6‐31G(d,p), B3LYP/ 6‐31++G(d,p), MPW1PW91/6‐31G(d,p), MPW1PW91/6‐31++G(d
## Abstract Theoretical calculations at the DFT level indicate that the reaction of a nitrone with a silyl ketene acetal proceeds, contrary to previous suggestions, through a classical 1,3‐dipolar cycloaddition, followed by a silyl group transfer step to give the open‐chain product. Introduction of