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Reaction mechanism change in the Lewis acid catalyzed perezone-pipitzol transformation

✍ Scribed by Sanchez, I. H.; Yanez, R.; Enriquez, R.; Joseph-Nathan, P.

Book ID
120989816
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
304 KB
Volume
46
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

On the mechanism of Dielsβ€”Alder reaction
On the mechanism of Dielsβ€”Alder reactions catalyzed by Lewis acids
✍ V. Branchadell; A. Oliva; J. Bertran πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 English βš– 261 KB

The effect of Lewis acid catalysts on the mechanism of Diels-Alder reactions is studied using the MINDO/3 method. It is found that they tend to increase the two-step character of the process through a more important participation of the charge-transfer configuration.