Reaction Kinetics of the Solid State Polymerization of Poly(bisphenol A carbonate)
β Scribed by Shi, Chunmei; Gross, Stephen M.; DeSimone, Joseph M.; Kiserow, Douglas J.; Roberts, George W.
- Book ID
- 127143259
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 72 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0024-9297
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π SIMILAR VOLUMES
The effect of prepolymer crystallinity on the solid-state polymerization (SSP) of poly(bisphenol A carbonate) was examined using nitrogen as a sweep fluid. A low-molecular-weight prepolymer was synthesized by melt transesterification and prepolymers with different crystallinities (11.7%, 23.3%, 33.7
## Abstract A simple kinetic model capable of describing the behaviors of solidβstate polymerization (SSP) of poly(ethylene terephthalate) (PET) has been developed. According to this model, there are two types of end groups, namely active end groups and inactive end groups, and the solidβstate poly