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Reaction Kinetics of Oxyphosphoranes with Model Compounds of Nucleosides

✍ Scribed by Xin Chen; Nan-Jing Zhang; Yu-Fen Zhao

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
251 KB
Volume
25
Category
Article
ISSN
0045-2068

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✦ Synopsis

Ester exchange reaction kinetics of oxyphosphoranes with several kinds of alcohols, the model compounds for nucleosides, has been investigated. Comparison of the reaction rates of oxyphosphorane (1) with alcohols indicated that the ester exchange rates of diols were much faster than that of monoalcohols. These results might provide a clue for the intrinsic difference between ribonucleotides and 2Ј-deoxyribonucleotides.

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