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Reaction kinetics of Mo(a7S3, a5S2, a5DJ, a5GJ) with O2

✍ Scribed by Mark L. Campbell; Roy E. McClean; James S.S. Harter

Book ID
103031295
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
418 KB
Volume
235
Category
Article
ISSN
0009-2614

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✦ Synopsis

The gas pi, ,,* -eactivities of Mo(a 753, a 552, a 5D~, a 5G.t) with 02 in the temperature range 297-620 K are reported.

Mo atoms were produced by the photodissociation of Mo(CO) 6 and MoCI 4 and detected by laser-induced fluorescence. The disappearance rates of all states arc found to be pressure independent with argon buffer gas. The disappearance rate constants of the sld s a753, aSS2 and aSGj states are on the order of the gas kinetic rate constant. The sZd 4 aSDj states are not as reactive and are found to be temperature dependent. Results are discussed in terms of the different electron configurations of the states.

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