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Reaction kinetics of cinnamoyl, .beta.-2-furylacryloyl, and .beta.-2-thienylacryloyl chlorides with anilines in benzene

✍ Scribed by Alberghina, G.; Arcoria, A.; Fisichella, S.


Book ID
127002566
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
468 KB
Volume
43
Category
Article
ISSN
0022-3263

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## Abstract Substitution reactions of 13 para‐ and meta‐substituted anilines with benzenesulfonyl chloride in varying mole fractions of benzene in propan‐2‐ol have been investigated conductometrically. The second‐order rate constants correlate well with pK~a~ values of anilines and with the Hammett