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Reaction kinetics of alkyl epoxides with DNA and other nucleophiles

✍ Scribed by Akseli Hemminki; Taneli Väyrynen; Kari Hemminki


Book ID
113137815
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
337 KB
Volume
93
Category
Article
ISSN
0009-2797

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Reactions of triarylmethyl carbocations
✍ C.A. Bunton; S.K. Huang; C.H. Paik 📂 Article 📅 1976 🏛 Elsevier Science 🌐 French ⚖ 233 KB

The N+ scale of nucleophilicity, evaluated from reactivities toward carbocationa, was initially interpreted in term of anionic desolvati0n.l The scale also fits diaeonium ion capture and deacylations, provided that allowauce is made for partitioning of tetrahedral intenuediatee. However, nucleophil