Reaction kinetics in hot-gas ignition of ethane-air
β Scribed by A.E. Bruszak; D. Burgess; M.H.J. Wijnen
- Publisher
- Elsevier Science
- Year
- 1963
- Tongue
- English
- Weight
- 595 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0010-2180
No coin nor oath required. For personal study only.
β¦ Synopsis
Heat balances were studied in a iet of heated nitroaen issuiw into cool ethane-air. Rates of heat production were obtazned io7 the oxidation of ethane-at low concentration near thk axis of the jet. Assuming the course of reaction to be unchanged at all temperatures (800D to 873%) and fuel concentrations used, the order of reaction-is unity with'respect to fuel and 0.25 with respect to oxygen. The activation energy is about 49 kcallmole. These values were tested by prediction of the hot-gas ignition temperature, assuming a purely thermal ignition, and by use in the Spalding centroid procedure to predict burning velocity.
π SIMILAR VOLUMES
A high temperature ethane oxidation model, based on the well-established kinetic model for ethane pyrolysis, has been developed. The reaction model comprises 69 reaction steps with 24 gaseous components. Numerical tests were carried out using experimental ignition delay data from shock tube measurem
System response S-curves for a hydrogen-air diffusion flame have been simulated numerically using detailed chemistry and transport. In particular, the globally nonpremixed ignition state has been studied in three distinct ignition regimes at pressures of 0.1, 1, and 10 atm. The role of heat release
Long-path FTlR spectroscopy was used to study the kinetics and mechanism of the reaction of CI atoms with CO in air. The relative rate constants at 298 K and 760 torr for the forward direction of the reaction of CI with I3CO and the reaction of CI1'C0 with 0, were hl = (3.4 2 0 8) X cm3 molecule-' s