✦ LIBER ✦
Reaction field simulations of the vapor-liquid equilibria of dipolar fluids: Does the reaction field dielectric constant affect the coexistence properties?
✍ Scribed by Benito Garzón; Santiago Lago; Carlos Vega
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 556 KB
- Volume
- 231
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Vapor-liquid equilibria of two Stockmayer fluids have been obtained by computer simulations in the Gibbs ensemble. The long-range dipolar interactions have been considered within the reaction field geometry. Two different criteria for the reaction field dielectric constant, tRF, have been applied. It is shown that t RF does not significantly affect either the coexistence properties or the structure of coexisting phases for the simulated systems.