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Reaction dynamics of the Ca(1D2, 3PJ) + RI → CaI + R (R  CH3, C2H5 and n-C3 H7) system: chemiluminescence, photon yield, electronic branching ratio and influence of the radical group

✍ Scribed by M. Garay; J.M. Orea; A. González Ureña

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
822 KB
Volume
207
Category
Article
ISSN
0301-0104

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📜 SIMILAR VOLUMES

Influence of the radical size on the Ca∗
Influence of the radical size on the Ca∗ + ROH → CaOH∗ + R (RCH3, C2H5 and C3H7) reaction cross section
✍ M. Esteban; M. Garay; J.M. García-Tijero; E. Verdasco; A.González Ureña 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 430 KB

Absolute values of the reaction cross section, CT,, for the title reaction family have been measured by chemiluminescence emission under beam-gas conditions. The uR values diminish as the radical group R increases in size, showing an important overall steric effect. These results are discussed in th

Reply to comment on “influence of the ra
Reply to comment on “influence of the radical size on the Ca∗ + ROH → CaOH∗ + R (R = CH3, C2H5 and C3H7) reaction cross section”
✍ A. González Ureña; M. Garay 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 105 KB

The argument given by Mestdagh et al. in their Comment is discussed in the light of previous work carried out by the same authors. In our Reply we emphasize that in addition to reaction energetics, dynamical and stereodynamical effects. could also decide the onset of a chemical reaction.