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Reaction between nitronium tetrafluoroborate and allyl esters

โœ Scribed by I. G. Mursakulov; A. G. Talybov; S. A. Parokhim; V. A. Smit

Book ID
112443194
Publisher
Springer
Year
1982
Tongue
English
Weight
540 KB
Volume
31
Category
Article
ISSN
1573-9171

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Formation of 1,3-dioxolenium salts by the AdE-reaction of nitronium Tetrafluoroborates with allyl esters
โœ I.G. Murskulov; A.G. Talybov; W.A. Smit ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 160 KB

Nitration of ally1 esters with N02BF4 proceeds with nucleophilic participation of carbonyl and yields nitro-substituted oxonium salts. Nitration of alkenes with N02BF4 1 may yield nitroalkenes 'a, 1,2-fluoronitroderivatives lb or solvoadducts I'. Here we report results showing that the interaction