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Reaction between alkyl isocyanides and isopropylideneMeldrum’s acid in the presence of bidentate nucleophiles

✍ Scribed by Issa Yavari; Maryam Sabbaghan; Zinatossadat Hossaini


Publisher
Springer
Year
2006
Tongue
English
Weight
224 KB
Volume
11
Category
Article
ISSN
1381-1991

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Reaction between alkyl isocyanides and d
✍ Issa Yavari; Abdolali Alizadeh; Mohammad Anary-Abbasinejad; Hamid R Bijanzadeh 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 105 KB

Protonation of the highly reactive 1:1 intermediates produced in the reaction between alkyl isocyanides and dibenzoylacetylene by saccharin, phthalimide, or 4-methyl-5-nitroimidazole, leads to vinylnitrilium cations, which undergo carbon-centered Michael type addition with the conjugate base of the