The photopolymerization of several di-and tetrafunctional (meth)acrylic monomers in the presence of a styrene-butadiene-styrene polymeric matrix (SBS) has been studied. Electron spin resonance spectroscopy (ESR) and differential scanning photocalorimetry (photo-DSC) were used as monitoring technique
✦ LIBER ✦
Reaction behaviour and kinetic constants for photopolymerizations of multi(meth)acrylate monomers
✍ Scribed by Kristi S Anseth; Cynthia M Wang; Christopher N Bowman
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 812 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0032-3861
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## Abstract The hydrated electron (e^−^~aq~) and hydroxyl radical rate constants with 18 acrylate‐, methacrylate‐, crotonate‐, fumarate‐ and maleate esters are discussed. The constants approach the diffusion‐controlled limit. __k__(e^−^~aq~) and __k__(OH) change in opposite direction; if __k__(e^−^