Re-Examination of Reversibility in Reaction Models for the Spontaneous Emergence of Homochirality
✍ Scribed by Blackmond, Donna G.; Matar, Omar K.
- Book ID
- 126963357
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 170 KB
- Volume
- 112
- Category
- Article
- ISSN
- 0022-3654
No coin nor oath required. For personal study only.
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## Abstract Asymmetric synthesis aims at obtaining enantio‐enriched products in stereoselective reactions under a chiral influence. We demonstrate both mathematically and numerically that, even under nominally achiral conditions, fully homochiral steady states can be obtained in open reactive syste
## Abstract Three different general strategies are proposed for kinetic models of the emergence of homochirality in open systems: flow‐through reactors, photochemical energy input, and chemical energy input from a sacrificial reagent. Using a simple, second‐order chiral autocatalytic core model, it