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Rb2BaNb2Se11: A new quaternary niobium polyselenide with infinite anionic chains composed of Nb2Se11 building block

✍ Scribed by Yuandong Wu; Christian Näther; Wolfgang Bensch


Book ID
104029750
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
343 KB
Volume
180
Category
Article
ISSN
0022-4596

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Synthesis, Crystal Structure, and Proper
✍ Peter Dürichen; Michael Bolte; Wolfgang Bensch 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 295 KB

Rb 12 Nb 6 Se 35 is the first ternary niobium polyselenide composed of infinite anionic chains. These are well separated by rubidium cations. It crystallizes in the orthorhombic space group Pbcn with unit cell dimensions a ‫؍‬ 8.5811(1) A s , b ‫؍‬ 13.7152(1) A s , c ‫؍‬ 56.5225(4) A s , and Z ‫؍‬ 4