✦ LIBER ✦

Rationally Designing Molecularly Imprinted Polymer towards Predetermined High Selectivity by Using Metal as Assembled Pivot

✍ Scribed by Songjun Li; Cong Liao; Wuke Li; Yifeng Chen; Xiao Hao

Book ID: 102471927
Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 485 KB
Volume: 7
Category: Article
ISSN: 1616-5187
DOI: 10.1002/mabi.200700047

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✦ Synopsis

Abstract

This article presents an original work aiming at rationally designing a molecularly imprinted polymer (MIP) towards high selective recognition. Assembled with (S)‐naproxen as a template and 4‐vinylpyridine as a functional monomer, a certain amount of cobalt, as pivot, is added for the preparation of MIP. The result indicates that the use of pivot plays obviously a positive role in increasing the specificity of MIP, so as to adsorb more for the template and less for its enantiomer. Related information indicates that this, in logic, can be a result of increasing match between binding sites and the templates, which makes the polymer capable of selectively recognizing the imprint species.

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