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Rationalization of scrambling processes among [C2H3O]+ ions

✍ Scribed by Ross H. Nobes; Leo Radom


Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
337 KB
Volume
21
Category
Article
ISSN
1076-5174

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πŸ“œ SIMILAR VOLUMES


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C,H,O]' ions with the initial structures [CH,CO]', [ICH,-CH=d]+ and [CH,CHO]' cannot be distinguished on the basis of their collisional activation spectra, demonstrating that these isomers interconbert at energies below their threshold for decomposition. Self-protonation of ketene leads to the [CH,C

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Specific Processes and Scrambling in the
✍ Maria Schlangen; Helmut Schwarz; Detlef SchrΓΆder πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 German βš– 188 KB πŸ‘ 1 views

## Abstract A mechanistically unprecedented situation characterizes the gas‐phase ion chemistry of Ni(C,H~3~,O)^+^ when reacted under thermal, single‐collision conditions with ethane. A dehydrogenation channel leading to Ni(C~3~,H~7~,O)^+^ is to 90% preceded by a complete loss of positional identit