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Rational Synthesis of Molybdenum(V) Tetramers Consisting of [Mo2O4]2+Dimers Held Together by Bridging Phosphinate Ligands and the Tungsten(VI) Dimer [(CH3O)2(O)W(μ-O)(μ-O2PPh2)2W(O)(CH3O)2]: Structural and Theoretical Considerations

✍ Scribed by Ampa Jimtaisong; Linsheng Feng; Soumya Sreehari; Craig A. Bayse; Rudy L. Luck


Publisher
Springer
Year
2007
Tongue
English
Weight
503 KB
Volume
19
Category
Article
ISSN
1040-7278

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## Cis -dioxo-metal complex ( NH,CHZCHZNHZ 12.s [ Md!i W6Y)Oz-(oc&O)2] 1 was obtained by the reaction of tetra-butyl ammonium hexamolybdotungstate with 1.2-dihydroxybenzene in the mixed solvent of CH3OH. CH3CN and ethylenediamine, and characterized by X-ray diffraction, UV-vis and EPR analysis. Co