Rational Design, Synthesis and Crystal Structure Investigation of Hydrogen-Bonded Coordination Polymers of Bicyclic Bis-Lactam Dicarboxylates

✍ Scribed by Denis A. Lenev; Konstantin A. Lyssenko; Remir G. Kostyanovsky

• Book ID: 102162695
• Publisher: John Wiley and Sons
• Year: 2003
• Tongue: English
• Weight: 212 KB
• Volume: 2003
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/ejic.200300115

✦ Synopsis

Abstract

The crystal structures of the racemic coordination polymers (±)‐1 to (±)‐4 and the coordination dimers (±)‐6 and (±)‐7, containing molecular “brick walls” with inorganic coatings and molecular “brick walls” with mixed organic‐inorganic coatings, respectively, were predicted and verified on the basis of the zigzag R~2~^2^(8) H‐bonded tape columnar packing motif of the purely organic racemic dialkyl 3,6‐dioxo‐2,5‐diazabicyclo[2.2.2]octane‐1,4‐dicarboxylates. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)