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Rational Design of Open-Framework Coordination Solids − Synthesis and Structure of [Co5(OH)2{1,2,4,5-(O2C)4C6H2}2(H2O)4]·xH2O

✍ Scribed by Siegfried O. H. Gutschke; Daniel J. Price; Annie K. Powell; Paul T. Wood


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
249 KB
Volume
2001
Category
Article
ISSN
1434-1948

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Coordination Chemistry of [Nb2(S2)2]4+ C
✍ M. Sokolov; A. Virovets; W. Clegg 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 151 KB 👁 1 views

Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space