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Rates of Solvolysis of the p -Nitrobenzoates of exo-endo Tertiary Norborneols. A Critical Examination of the exo-endo Rate Ratio as a Basis for the Postulated Nonclassical Structure of the Norbornyl Cation

โœ Scribed by Brown, Herbert C.; Chloupek, Frank J.; Rei, Min-Hon.


Book ID
127136378
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
401 KB
Volume
86
Category
Article
ISSN
0002-7863

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Stereoelectronic control of exo/endo rat
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The variable exo/endo rate ratios observed in the solvolysis of 6-exosubstituted exo-and endo-2-norbornyl p-toluenesulfonates are due to differential transmission of polar effects in the transition state for ionization.