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Rates of dediazoniations of arenediazonium ions complexed with 18-, 21- and 24-membered crown ethers

โœ Scribed by Hiroyuki Nakazumi; Ivanka Szele; Heinrich Zollinger


Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
198 KB
Volume
22
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


The evaluation of the kinetics of dediazoniation of benzenediazonium tetrafluoroborate and p-chlorobenzenediazonium tetrafluoroborate in 1,2-dichloroethane at 50ยฐC in the presence of 18-crown-6,


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Ion-pair formation in water Distribution of cadmium ion-pair complex into benzene Cadmium picrate Crown ethers Potentiometry with ISE Overall ion-pair formation constants (ฮฒ 2 /mol -2 dm 6 ) of CdL 2+ with picrate ion (Pic -) and Cl -in water (w) were determined at 298 K potentiometrically, where L