Rates of alkylation of metal, enolates of 2,6- and 2,2-dimethylcyclohexanone

✍ Scribed by Drury Caine; Byron J.L. Huff

• Book ID: 104241117
• Publisher: Elsevier Science
• Year: 1967
• Tongue: French
• Weight: 265 KB
• Volume: 8
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)89852-x

✦ Synopsis

We have determined the rates of algylation of the potassium and lithium enolates of 2,6-(I) and 2,2-dimethylcyclohexanone(II), that is, III and IV. The relative reactivities of these species and the manner in which the change in metal cation influences them is of interest in connection with the general problem of amlation of metal enolates of cyclohexanone derivatives.