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Rates of addition and deprotonation in reactions of ferrocenylalkylium ions with nucleophiles

โœ Scribed by Clifford A. Bunton; William E. Watts


Book ID
104235974
Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
269 KB
Volume
18
Category
Article
ISSN
0040-4039

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Reactions of 5-(alkoxy)thianthrenium perchlorates (1) with weakly basic nucleophiles Br ร€ , I ร€ and PhS ร€ (X ร€ ) in MeCN and DMSO led to S N 2 substitution, E2C elimination, and reaction at sulfonium sulfur to extents depending on the structure of the alkoxy group (RO) in 1 and the nucleophile. Thre