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Rates of acid-catalyzed geometric isomerization of some compounds containing a carbon-nitrogen double bond

✍ Scribed by Johnson, James Elver; McPeters Silk, Nancy; Arfan, Mohammed


Book ID
126223992
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
521 KB
Volume
47
Category
Article
ISSN
0022-3263

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Structural organic chemistry by nmr. III
✍ N.P. Marullo; E.H. Wagener 📂 Article 📅 1969 🏛 Elsevier Science 🌐 French ⚖ 226 KB

There are two possible limiting mechanisms by which compounds containing the carbonnitrogen double bond can thermally isomerize. One of these, proposed for the isomerization of imines2, involves a lateral in-plane shift of the group bonded to the imino nitrogen. The transition state for this proces