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Rates and Mechanisms of Water Exchange of UO 22+ (aq) and UO 2 (oxalate)F(H 2 O) 2- : A Variable-Temperature 17 O and 19 F NMR Study

✍ Scribed by Farkas, Ildikó; Bányai, István; Szabó, Zoltán; Wahlgren, Ulf; Grenthe, Ingmar


Book ID
120934340
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
94 KB
Volume
39
Category
Article
ISSN
0020-1669

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Water exchange on [Gd(H2O)8]3+ and [Gd(P
✍ Károly Micskei; D. Hugh Powell; Lothar Helm; Ernö Brücher; André E. Merbach 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 956 KB

## Abstract ^17^O NMR longitudinal and tranverse relaxation rates and chemical shifts were measured at variable temperature at three magnetic fields (1.4, 4.7 and 9.4 T) for aqueous solutions of the complexes [Gd(H~2~O)~8~]^3+^ and [Gd(PDTA)(H~2~O)~2~]^−^. The transverse relaxation rates and chemic