Rates and activation parameters for the stepwise formation of mono complexes of the hexakis(dimethyl sulphoxide)aluminium(III) ion with uni-, bi-, and ter-dentate nitrogen-donor ligands in nitromethane solution

Stopped-flow fourier-transform NMR and N

Stopped-flow fourier-transform NMR and NMR line broadening studies of the rates of dimethyl sulphoxide exchange with the hexakis(dimethylsulphoxide) complexes of aluminium(III), gallium(III) ions in nitromethane solution

✍ André E. Merbach; Peter Moore; Oliver W. Howarth; Colin H. McAteer 📂 Article 📅 1980 🏛 Elsevier Science 🌐 English ⚖ 685 KB

Stopped-flow Fourier-transform NMR and conventional NMR line broadening experiments have been used to determine rate data for dimethyl sulphoxide (DMSO) exchange with the [M(DMSO),] " ions (M = Al(III), Ga(III)) in nitromethane-d3 solution over a temperature range of 105 K (Al/III)) and 112 K (Ga-(I