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Rate processes and carbon-13 magnetic resonance spectra. Hindered internal rotation of N,N-dimethyltrichloroacetamide

✍ Scribed by Gansow, Otto A.; Killough, John; Burke, Aaron R.

Book ID
125986089
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
244 KB
Volume
93
Category
Article
ISSN
0002-7863

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## Abstract The NMR variable temperature behaviour of __N__‐aroyl‐ and __N__‐thioaroyl‐__N__′‐piperonylpiperazines was investigated. The largest chemical shift separation between the exchanging methylene groups, and the highest energy barrier, is found for the thioamide compounds. Results from semi