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Rate of electron transfer between tris(dithiocarbamato) complexes of iron(III) and iron(IV) by proton magnetic resonance

โœ Scribed by Palazzotto, M. C.; Pignolet, L. H.


Book ID
120191231
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
430 KB
Volume
13
Category
Article
ISSN
0020-1669

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The rate of the electron-exchange betwee
โœ I. Ruff; M. Zimonyi ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 193 KB

The rate of the electron-exchange between ferroin and ferriin ions, unmeasurably fast for methods known so far, has been determined by the application of transfer diffusion. The second order rate constant proved to be (3.3 f 1.4) x lOs/M/s. The rate constant calculated by accounting for the electros