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Rate of deprotonation of phenylnitromethane by hydroxide ion in aqueous dimethyl sulfoxide and aqueous methanol

✍ Scribed by Slater, Carl D.; Chan, Yau Wai


Book ID
127296341
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
536 KB
Volume
43
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


Kinetics and mechanism of oxidation of d
✍ D. S. Mahadevappa; M. B. Jadhav; H. M. K. Naidu πŸ“‚ Article πŸ“… 1979 πŸ› John Wiley and Sons 🌐 English βš– 569 KB

## Abstract The kinetics of oxidation of dimethyl sulfoxide (DMSO) by chloramine‐T (CAT) is studied in HClO~4~ and NaOH media with OsO~4~ as a catalyst in the latter medium. In acid medium, the rate law is ‐__d__ [CAT]/__dt__ = __k__ [CAT][DMSO][H^+^]. Alkali retards the reaction and the rate law t